ORGANIC MATTER IN THERMAL, COLD GROUND AND SURFACE WATERS OF THE FAR EAST SOUTH CONTINENTAL PART (OXYGEN-CONTAINING COMPOUNDS)

V.A. Poturay

Аннотация


This article presents the composition and molecular weight distribution of medium volatility oxygen-containing organic compounds in the thermal, cold ground and surface waters of the continental part of the Far East south. Using the method of capillary gas chromatography-mass spectrometry, it is found 71 oxygen-containing compounds in thermal waters, belonging to 10 homologous series, and in cold ground and surface waters – 36 compounds, belonging to 7 homologous series. Their relative content in the medium volatility organic matter composition is about 55% in thermal waters and about 45% in cold ground and surface waters. Esters, carboxylic acids and aldehydes are widespread in hot waters. These compounds are widely produced in the biosphere and are probably of biogenic origin. The features of the carboxylic acids and aldehydes molecular weight distribution (the predominance of homologues with an even number of carbon atoms in the molecule) also show their biogenic genesis. The formation of ethers can as well be associated with the oxidation of organic matter in water-bearing rocks, and aromatic and nitrogen-containing components – with thermogenic processes occurring in hydrothermal systems. Esters, steroids and ketones also reach their maximum relative concentrations in cold waters. Steroids predominate in the oxygen-containing organic compounds composition in cold ground and surface waters where the carboxylic acids distribution is insignificant. Among the revealed compounds, in thermal waters there are some components – indicators of technogenic pollution. These are the compounds containing a tert-butyl group and DETA. However, their share in the composition of medium volatility organic matter is insignificant. 

Ключевые слова


hydrothermal system; thermal water; cold water; organic matter; genesis

Литература


Artemenko A.I. Organicheskaya khimiya: uchebnik dlya stroitel'noi spetsial'nosti vuzov (Organic chemistry: a textbook for the construction specialty of universities). 5-e izd., ispr. Moscow: Vyssh. Shk. Publ., 2002. 559 p. (In Russ.).

Arkhipov B.S. Chemical composition and metal content 0f thermal waters of the north-eastern Sikhote-Alin (Far East). Russian Journal of Pacific Geology, 2009, vol. 28, no. 4, pp.116–122. (In Russ.).

Barabanov L.N., Disler V.N. Azotnye termy SSSR (Nitrogen baths of the USSR). Moscow: Geominvod Publ., 1968. 119 p. (In Russ.).

Bogatkov N.M. Kuldur Baths. Sovetskaya geologiya, 1962, no. 8, pp. 157–161. (In Russ.).

Bragin I.V., Chelnokov G.A. Geochemistry of Sikhote-Alin thermal waters. Gas aspect. Vestnik DVO RAN, 2009, no. 4, pp. 147–151. (In Russ.).

Veselova M.A., Plyuta V.A., Khmel' I.A. Volatile compounds of bacterial origin: structure, biosynthesis, and biological activity. Microbiology, 2019, vol. 88, no. 3, pp. 261–274. DOI: 10.1134/S0026365619030169. (In Russ.).

Gidrogeologiya SSSR. T. 23. Khabarovskii krai i Amurskaya oblast' (Hydrogeology of the USSR. Vol. 23. Khabarovsk Territory and Amur Region). Мoscow: Nedra Publ., 1971. 514 p. (In Russ.).

Kalitina E.G. Microorganisms of Primorye Thermal Waters as Indicators of Anthropogenic Pollution. Vestnik Orenburgskogo gosudarstvennogo universiteta, 2013, no. 10 (159), pp. 136–138. (In Russ.).

Kalitina E.G., Kharitonova N.A., Vakh E.A. Distribution of bacteria of various ecological and trophic groups in the underground thermal waters of the Kuldur deposit (Russian Far East). Sovremennye problemy nauki i obrazovaniya, 2017, no. 5, pp. 351. (In Russ.).

Kompanichenko V.N., Poturay V.A. Variations in organic matter composition in waters of the Kuldur thermal field, the Far East of Russia. Russian Journal of Pacific Geology, 2015, vol. 34, no. 4, pp. 96–107. (In Russ.).

Kulakov V.V. Geological-structural and hydrothermal conditions for the formation of groundwater in Priamurye. Russian Journal of Pacific Geology, 2014, vol. 33, no. 5, pp. 66–79. (In Russ.).

Kulakov V.V. Geokhimiya podzemnykh vod Priamur'ya (Geochemistry of groundwater in Priamurye). Khabarovsk: IVEP FEB RAS, 2011. 254 p. (In Russ.).

Melenevskii V.N., Kashirtsev V.A., Leonova G.A., Bobrov V.A., Krivonogov S.K. Transformation of organic matter in the holocene sediments of lake Ochki (south Baikal region): evidence from pyrolysis data. Geochemistry international, 2015, vol. 53, no. 10, pp. 925–944. DOI: 10.7868/S0016752515080051. (In Russ.).

Ostroukhov S.B. Genesis of higher petroleum alkyltoluenes. Petroleum Chemistry, 2018, vol. 58, no. 1, pp. 8–12. DOI: 10.7868/S0028242115030090. (In Russ.).

Poturay V.A. Oxygen-containing organic compounds in thermal waters of the Mutnovsky and Paratunsky geothermal areas and сaldera Uzon, Kamchatka. Regional'nye problemy, 2020, vol, 23, no. 2, pp. 32–38. (In Russ.). DOI: 10.31433/2618-9593-2020-23-2-32-38. (In Russ.).

Poturay V.A. Organic matter in hydrothermal systems of the Far East of different types and situations. Bulletin of the Tomsk Polytechnic University. Geo Assets Engineering, 2018, vol. 329, no. 11, pp. 6–16. DOI: 10.18799/24131830/2018/11/204. (In Russ.).

Poturay V.A. Organic matter in ground- and surface waters in the area of the Annenskii geothermal field, Russian Far East. Geochemistry International, 2017, vol. 55, no. 4, pp. 393–400. DOI: 10.7868/S0016752517020054. (In Russ.).

Poturay V.A. Composition and distribution of n-paraffines in nitrogen thermal waters of the Russian Far East. Russian Journal of Pacific Geology, 2017, vol. 36, no. 4, pp. 109–119. (In Russ.).

Poturay V.A., Strochinskaja S.S., Kompanichenko V.N. Complex biogeochemical characteristics of the Tumnin springs thermal water. Regional'nye problemy, 2018, vol. 21, no. 1, pp. 22–30. (In Russ.).

Rapoport V.L., Kondrat'eva L.M. Pollution of the Amur River by anthropogenic and natural organic matter. Sibirskii ekologicheskii zhurnal, 2008, no. 3, pp. 485–496. (In Russ.).

Ukraintsev A.V., Plyusnin A.M. Aliphatic hydrocarbons of carbon dioxide mineral and nitrogen thermal waters of Western Transbaikalia, in Geologicheskaya evolyutsiya vzaimodeistviya vody s gornymi porodami (Geological evolution of the interaction of water with rocks). Ulan-Ude: BSC SB RAS, 2020, pp. 179–183. DOI: 10.31554/978-5-7925-0584-1-2020-179-183. (In Russ.).

Shvartsev S.L. Obshchaya gidrogeologiya (General hydrogeology). Мoscow: Nedra Publ., 1996. 423 p. (In Russ.).

Fekete J., Sajgó C., Kramarics Á., Eke Z., Kovács K., Kárpáti Z. Aquathermolysis of humic and fulvic acids: Simulation of organic matter maturation in hot thermal waters. Org. Geochem., 2012, vol. 53, pp. 109–118. DOI: 10.1016/j.orggeochem.2012.07.005.

Gonzalez-Barreiro C., Cancho-Grande B., Araujo-Nespereira P., Cid-Fernandez J.A., Simal-Gandara J. Occurrence of soluble organic compounds in thermal waters by ion trap mass detection. Chemosphere, 2009, no. 75, pp. 34–47.

Hunt J.M. Petroleum geochemistry and geology. San Francisco: W.H. Freeman and Company, 1979. 617 p.

McCollom T.M., Seewald J.S., Simoneit B.R.T. Reactivity of monocyclic aromatic compounds under hydrothermal conditions. Geochimica Cosmochimica Acta, 2001, vol. 65, pp. 455–468.

Poturay V.A. Alkanes in a number of hydrothermal systems of the Russian Far East. E3S Web of Conferences, 2019, vol. 98, 02008. DOI: 10.1051./e3sconf/20199802008.

Sanchez-Avila J.I., Garcia-Sanchez B.E., Vara-Castro G.M., Kretzschmar T. Distribution and origin of organic compounds in the condensates from a Mexican high-temperature geothermal field. Geothermics, 2021, vol. 89, 101980. DOI: 10.1016/j.geothermics.2020.101980.

Shorland F.B. Occurrence of fatty acids with uneven-numbered carbon atoms in natural fats. Nature, 1954, no. 174, 603 p.

Tassi F., Venturi S., Cabassi J., Capecchiacci F., Nisi B. Vaselli O. Volatile organic compounds (VOCs) in soil gases from Solfatara crater (Campi Flegrei, southern Italy): geogenic source(s) vs. Biogeochemical processes. Applied Geochemistry, 2015, vol. 56, pp. 37–49.


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